(E)-Methyl 2-chloro-4-dicyclohexylamino-4-oxobut-2-enoate

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(E)-Methyl 2-chloro-4-dicyclo­hexyl­amino-4-oxobut-2-enoate

In the title compound, C(17)H(26)ClNO(3), both cyclo-hexyl rings have chair conformations. In the crystal, mol-ecules are linked by weak inter-molecular C-H⋯O hydrogen bonds.

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(E)-Ethyl 2-benzoyl-4-(naphthalen-2-yl)-4-oxobut-2-enoate

The title compound, C(23)H(18)O(4), is a 1,4-enedione compound which contains a naphthalene ring and a benzene ring. The dihedral angle between the ring systems is 74.9 (2)°. In the crystal, the mol-ecules form π-π stacking inter-actions between naphthalene rings of inversion-related mol-ecules, with an inter-planar spacing of 3.499 (2) Å.

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Crystal structure of ethyl (E)-4-(4-chlorophen­yl)-4-meth­oxy-2-oxobut-3-enoate

In the title compound, C13H13ClO4, the dihedral angle between the chloro-benezene ring and the least-squares plane through the 4-meth-oxy-2-oxobut-3-enoate ethyl ester residue (r.m.s. deviation = 0.0975 Å) is 54.10 (5)°. In the crystal, mol-ecules are connected by meth-oxy-ketone and benzene-carboxyl-ate carbonyl C-H⋯O inter-actions, generating a supra-molecular layer in the ac plane.

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(E)-4-Chloro-N-[(E)-2-methyl-3-phenyl­allyl­idene]aniline

The title Schiff base compound, C(16)H(14)ClN, adopts E configurations with respect to both the C=C and C=N bonds. The dihedral angle between the two aromatic rings is 53.27 (4)°, while the plane through the C=C-C=N system is inclined at 9.06 (8)° to the benzene ring and 44.92 (5)° to the chloro-benzene ring. In the crystal structure, weak C-H⋯Cl and C-H⋯N hydrogen bonds stack the mol-ecules do...

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rac-Ethyl (2Z)-3-{2-[(Z)-4-eth­oxy-4-oxobut-2-en-2-yl­amino]­cyclo­hexyl­amino}­but-2-enoate

The asymmetric unit of the title compound, C(18)H(30)N(2)O(4), contains two independent mol-ecules. In each mol-ecule, the cyclo-hexane ring adopts a chair conformation with equatorial orientation of the substituents, and the conformation is stabilized by two intra-molecular N-H⋯O hydrogen bonds, forming rings of S(6) graph-set motif. One eth-oxy group and one ethyl group are disordered over tw...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811027760